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Currents--University of Rochester newspaper

Researchers unravel matter mystery

University researchers have created a mathematical model that will allow scientists to simulate and understand phase change--the transformation process of matter moving from one phase to another, such as from liquid to gas. This breakthrough could have an impact on everything from decaffeinating coffee to improving fuel cell efficiency in automobiles of the future.

"This problem has baffled scientists for decades," says Yonathan Shapir, professor of physics and of chemical engineering who is coauthor of the paper published in Physical Review Letters. "This is the first time a computer program could simulate a phase transition because the computers would always bog down at what's known as the 'critical slowdown.' We figured out a way to perform a kind of end-run around that critical point slowdown and the results allow us to calculate certain critical point properties for the first time."

Everyone knows what happens to water when it boils--everyone, that is, except computers. Modeling phase change has been all but impossible near the critical point due to the increasingly complex way molecules behave as they approach the change from one phase to another. "Critical slowdown" is a phenomenon that happens as matter moves from one phase to another near the critical point. As molecules in a gas, for instance, are cooled, they lose some of their motion, but are still moving around and bumping into each other. As the temperature drops to where the gas will change into a liquid, the molecules' motion becomes correlated, or connected, across larger and larger distances. That correlation is a bit like deciding where to go to dinner--quick and easy with two people, but takes forever for a group of 20 to take action. The broadening correlation dramatically increases the time it takes for the gas to reach an overall equilibrium, and that directly leads to an increase in computing time required, approaching infinity and bogging down as the gas crosses the point of phase change.

The research team of Eldred Chimowitz, professor in the Department of Chemical Engineering, Shapir, and physics graduate student Subhranil De created a novel approach to tackle the phase-change process. They devised a computational model consisting of two separate reservoirs of fluid at equilibrium and near the critical point threshold. One reservoir was slightly more pressurized than its neighbor. The reservoirs were opened to each other, and the pressure difference caused the fluids to mix. The team let the simulation run until the entire system reached thermodynamic equilibrium. By watching the rate that equilibrium returned, the team was able to calculate the behavior at the critical point. Their simulation findings match predictions and experimental results, including very precise measurements performed in microgravity on the Space Shuttle.

"In principle, it's a difficult calculation," says Chimowitz, who has just published a much-praised book about the subject, called Introduction to Critical Phenomena in Fluids from Oxford University Press. "Fluid systems require a different class of models than the common lattice models used by researchers who have studied dynamic critical behavior. These different classes give rise to different dynamic critical exponents and we found them, for the first time, in real fluid systems."

The best known examples of phase changes are perhaps water to ice and water to steam. Phase changes of many different physical types occur, however, such as the separation of a liquid mixture to its components, which should also abide by the Rochester team's results.

The team's simulation approach will likely be used by industry in a variety of ways, not the least of which will be to derive more power from a fuel cell. Since fuel cells rely on the transportation of protons through a membrane separating two electrodes, Shapir and Chimowitz believe it should be possible to use their work to find the most efficient configurations for a fuel cell. Other applications, such as removing the caffeine from coffee, work in a similar way and will likely also benefit.



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